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Are you asking for information on how to insure that the LOs for I and Q are 90 degrees apart?
One trick is to use an analog diode ring mixer. Put one of your oscillators to the LO and the other to the RF port of the mixer. You should get 0 V out if they are 90 degrees apart. Make sure to measure the mixer output offset voltage by first making the RF input from a 50 ohm resistor. Subtract this value from the reading you get with the other LO signal to the RF.