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These old PCBs I am aware of, did not have a solder mask at all. The traces were either gold plated of tin plated and the FR4 was bare, no solder mask.Hi,
never thought about the color of the FR4 base material...
Usually the color of a PCB is dominated by the solder resist color.
Maybe the base material color really is different, but there also may be other reasons:
* copper plating or not
* blackened copper traces (Some decades ago one chemically blackened copper traces for better solder resist bonding. Maybe they also blackened the base materieal side of the copper. Don´t know)