The TDA5051 was designed for transmitting/receiving digital signals on power lines or any two-wire network, so if the units will be connected to the building’s electrical wiring system via a 120V/230V outlet, connect one wire line to pin 14/10 (via capacitors, see the datasheet) and the second one directly to pins 5/9/12, at the end this means it doesn't matter how to connect the outputs to the power lines.
And there’s no guarantees you will have a good communication in-between devices for a three phase system, actually system was design to plug into other outlets among the same wiring system, so communication for a three phase system depends on the local configuration and the noise conditions on the power lines.