I presume, the bias voltage polarity is meaned as shown in the schematic. It has been BTW copied from a competitor's application note :grin:
The voltage level is specified with 300 mV, sensor referred. This popular potentiostat circuit needs a dual voltage supply, and could work with LM741. Considering the fact that the circuit should be permanently (battery) powered to avoid long equilibration periods after starting the instrument, you'll preferably use a micropower OP.