If you place a charge at the "gate surface" - i.e. at the gate and the gate dielectric interface (or inside the gate or at any other surface of the gate electrode), it will be screened by free carriers in the gate material.
You won't see any effect on any electrical characteristics.
But if you place it at the gate dielectric - semiconductor interface - you will see an effects (such as Vt shift), proportional to charge value.
Check with your TCAD tool manual, where you place the charge.