Dear cdbular,
For making RS-232 communication using C/C++ I suggest you the book "C Programmer`s Guide To Serial Communication" By CAMPBELL. This is a ultimate book I think. You will find lot of info. for serial communication. Also lot of code written in C/C++.
This is a simple code. If u have a serial cable and you connect the Pin No. 2 and 3 together.... which are actually trans and receive.... than u can run this and check.
It sends a number or character(1 byte only) and receives it and displays it.
have fun...