Extraction of intrinsic and extrinsic components is not easy from s-parameters.
For that target, modelling softwares are more useful but they are not available in a reasonable prices.Measurement equipments are also very expensive.
Instead, you may see modelled components by making a simple DC simulation at that operating point since the appropriate model is well known.Cadence ADE gives you almost these components and ADS gives you some important intrinsic parameters in Simulation-->Detailed Operating Point option but not all of them.