see the article PIC to PS/2 Mouse and Keyboard Interfacing which came in the August 2004 issue of EPE. it shows how to use a PS/2 with a PIC microcontroller.
PS/2 is not the same as RS-232.
RS-232 hase transmission line (Tx) and reception line (Rx) +/-3 to +/-25V whereas PS/2 has Data line and Clock line, both 0-5V levels.