hi,
to modify pc PSU you need to search a voltage divider around the 12 v output (or 5 v output). This voltage divider feeds some voltage beck to an IC placed somewhere close to the region you searched. By modifying the values of the resistors of the divider you can go up to 14 V if the unit does not have an over voltage protection stage (if it has, you have to deactivate it ... it is better to get an other pc psu without that...).
Be careful when modifying the resistors from the voltage divider, if open loop appears between output of the divider and the supply of the divider (i mean the superior resistor), risc of electric shock may appear (the Ic which get's the voltage signal thru this voltage divider from the output of the PSU, does not see the output voltage anymore -doe to the open loop-, and gives high gain to its next stage ..............beside the voltage regulator loop it may have a current regulator loop to..........)
About the charging current it is about ~ 4 A .
A safe alternative would be to make a traditional battery charger with transformer ..... it cost's a little, it's heavy but work's fine . The pc PSU is a cheap alternative ( I use it to :wink: ) , and you need to take care of the charging current, if to high , the PSU can deactivate (the cooler stops) It is indicated to measure that current to get an idea about the status of your battery.....