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The ML.EXE itself has its command line options described at
Moreover, if you are interested in MS manual itself - mainly for DOS programming -, its copy is available at hxxp://webster.cs.ucr.edu/Page_TechDocs/MASMDoc/ (ony figures are 'missing'). (And also for those interested in Win32 programming hxxp://www.movsd.com could be valuable source of information.)