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If it doesn't have significant leakage or series resistance, you can sweep it with a voltage ramp and plot the current.
I=C*dv/dt, therefore, C=I/(dv/dt). Set dv/dt to some convenient number such as 1v/usec (1e6), so that you only have to apply a power of ten scale factor. I have done this, and it works well, at least in simulations.
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