I don't think, in your case, it is a good idea to create an intermediate voltage of 5V ..
Have a look at this option:
h**p://www.national.com/ds/LM/LM2576.pdf (3A, or 2575 for 1A)
These regulators can be fed directly from +12V ..
For 3.3V you can select LM2576-3.3V.
For 5V and less then 1A, you can select LM2575-5.0V.
For other voltages you can select LM2576/5-ADJ (stands for sdjustable) and, using one additional regulator per voltage required, adjust them as follows: 2.5V, 1.9V and 1.2V ..
Regards,
IanP