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I'm not sure where to put/save the file.csv file.
In the search path for files. If you don't know this path, insert an absolute (full) path name, or a relative one (for better portability): relative to the directory where from you started the Synopsys Schematic Editor.
Make sure the .csv file isn't separated by commas, but by white space.
... looks more like a wrong (even an invisible (control)) character, possibly. Check the characters before this "2".syntax error at or before "2"